Abstract
The high resolution Fourier transform infrared spectra of the ν 5, ν 6, ν 11, and ν 8 + ν 11 bands of triacetylene have been recorded. More than 1300 transitions have been assigned using an interactive Loomis-Wood program to facilitate the rovibrational analyses of these bands and their associated hot bands. The ground and excited state rotational and centrifugal distortion constants together with band origins and vibration-rotation parameters are presented. The ground state rotational constant, B 0, of 0.04417223(15) cm −1 is compared with B e values obtained from ab initio calculations and with a B value calculated from an expected geometry of triacetylene based on the known r s geometry of HC 5N.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
