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Abstract
Abstract 1-Chloro-2-methyl-N,N-tetramethylenepropenylamine was found to be a good condensation reagent for the regioselective coupling reaction of allylic alcohols with lithium enolate of dithioesters under mild conditions to afford γ,δ-unsaturated dithioesters, which proceeds by a thio-Claisen rearrangement of S-allylic ketene dithioacetals initially formed.
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