Abstract
Using FTIR spectroscopy − (60.3±2.5) kJ·mol −1 has been obtained for the heat of dimerization of gaseous acetic acid and (110±4) kJ·mol −1 has been obtained for the heat of decomposition of solid ammonium acetate into the gases ammonia and acetic acid monomer. The former value agrees well with previous studies where errors due to wall adsorptions were avoided. The value for the decomposition of ammonium acetate is the first to be directly determined by experiment.
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