Abstract
The heat capacity and density of solutions of cadmium and mercury diiodides in methylpyrrolidone (MP) at 298.15 K were studied by calorimetry and densimetry. The data obtained are discussed in relation to the special features of solvation and complex formation in solutions of the salts. The standard partial molar heat capacities and volumes ( Open image in new window and Open image in new window ) of the electrolytes in MP were calculated. The standard heat capacities Open image in new window and volumes Open image in new window of the Cd2+ and Hg2+ ions in solutions in MP at 298.15 K were determined.
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