Abstract
The microwave spectra of three isotopic species of chloryl fluoride, FClO 2, previously published by Parent and Gerry ( J. Mol. Spectrosc., 49, 343–364 (1974)), have been refit to rotational constants and centrifugal distortion constants using Watson's Hamiltonian in both its A and S reductions. The quartic distortion constants have been combined with the vibrational data of Smith, Begun, and Fletcher ( Spectrochim. Acta, 20, 1763–1770 (1964)) to calculate a refined harmonic force field. The rotational constants and force field have been used to calculate a zero-point average structure and an approximate equilibrium structure. Both the force field and structures are in essential agreement with those published earlier.
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