Abstract

Epitaxial layers of aluminium nitride have been grown on corundum substrates by vapour phase deposition, with aluminium chloride and ammonia as reactants. The structural perfection of the AIN material thus formed has been assessed using optical, X-ray diffraction and electron diffraction techniques. Although some oriented and unoriented polycrystalline deposits have been found, many highly oriented or single crystal layers have been produced. The two main epitaxial relationships developed are (2 1 1 0) A1N//(01 1 2) A1 2O 3 and (2 1 1 6) A1N//(01 1 2) A1 2O 3. The factors which govern the occurrence of these relationships are discussed. Measurements of the piezoelectric coupling of aluminium nitride on α-A1 2O 3 have been made and simple delay lines have been fabricated.

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