Abstract

Single crystal platelets of Cd3As2 having carrier concentrations less than 1024 m−3 have been grown from the vapour in the presence of argon gas and excess cadmium vapour. It is shown that the resistivity and Hall data is consistent with a band model in which there is a direct band-gap atk=0 of approximately 0.38 eV and an indirect zero band-gap. It is suggested that the large electron carrier concentrations usually present in Cd3As2 result from anti-structure disorder.

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