Abstract
The use of recently determined highly precise inertial data for various isotopic modifications of methyl isocyanide has enabled the ground-state average, or rz, structure to be determined to within very narrow limits. Harmonic corrections to ground-state rotational constants have been calculated using a high-quality, experimentally determined harmonic force field. The derived zero-point inertial constants are sufficiently accurate to enable changes in the CH bond length and NCH bond angle on deuteration to be determined. The present rz structure determination is believed to be a physically realistic estimate of the ground-state average geometry of methyl isocyanide.
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