Abstract
A compressed knotted ring polymer in a confining cavity is modelled by a knotted lattice polygon confined in a cube in . The GAS algorithm (Janse van Rensburg and Rechnitzer 2011 J. Knot Theol. Raman 20 1145–71) is used to sample lattice polygons of fixed knot type in a confining cube and to estimate the free energy of confined lattice knots. Lattice polygons of knot types the unknot, the trefoil knot, and the figure eight knot, are sampled and the free energies are estimated as functions of the concentration of monomers in the confining cube. The data show that the free energy is a function of knot type at low concentrations, and (mean-field) Flory–Huggins theory (Flory 1942 J. Chem. Phys. 10 51–61; Huggins 1942 J. Phys. Chem. 46 151–8) is used to model the free energy as a function of monomer concentration. The Flory interaction parameter of knotted lattice polygons in is also estimated.
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