Abstract

Platinum(II) chloride or lithium chloroplatinate(II) react with N,N-dimethyl-2-methylallylamine to give 2-methyl-3-(dimethylamino)propenylplatinum(II) chloride dimethylamine in 46% yield. Treatment of this compound with either triphenylphosphine or aniline causes elimination of dimethylamine and gives the corresponding triphenylphosphino or anilino complex.

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