Abstract
Sulfene, generated from methanesulfonyl chloride and triethylamine in acetonitrile reacts with itself to form a tetramer which may be isolated as an acyclic crystalline pyridinium sulfonate salt, 1. When sulfene is generated in tetrahydrofuran in the presence of pyridine, the 1,1,3,3-tetraoxide of 4,4a-dihydropyrido[1,2-d][1,5,2]dithiazine, 11, is formed. Structural evidence (including nmr and mass spectra) for these compounds, for homologs of 11, and for a series of acyclic polysulfonyl compounds derived from 1 is presented. An X-ray crystal structure determination was carried out on 9, the 5,7-dimethyl homolog of 11.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
