Abstract
Thermal treatment of a solution of Ru 3(CO) 12 and C 5H 5Me 2SiC 5H 5 in heptane gives (Me 2Si)[(η 5-C 5H 4)Ru(CO)] 2(μ-CO) 2 ( 1) in good yield. An investigation on the infrared spectra of 1 in KBr disc and CH 2Cl 2 solution reveals the coexistence of two isomers 1a (bridging form) and 1b (non-bridging form), with the former dominant. The molecular structure of 1a has been determined by X-ray diffraction.
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