Abstract
MOFs including non-coordinating POMs as a template are rare. We report here the first four-fold interpenetrated POM-templated 3D MOF [Cu(3)(4,4'-bpy)(5)](2)[H(2)SiW(11)O(39)] x 5H(2)O, whose framework topology is previously unknown with the vertex symbol (6 x 6 x 8(2))(2)(6 x 6 x 8 x 8 x 10(6) x 10(6)).
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