Abstract

A new BEDT-TTF-based organic salt with a ferrocene-containing dianion has been prepared: β″-(BEDT-TTF)4(Fe(Cp-CONHCH2SO3)2)·2H2O. The salt shows metallic behaviour from 300 to 70 K, followed by a sharp metal–insulator transition. The transition is suppressed by applying a static pressure of 9.5 kbar.

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