Abstract
The first organic–inorganic hybrid compound based on the Keggin polyoxometalate and alkali-N-heterocycle ligand [Na4(tib)2(H2O)2(α-HBW12O40)]·2H2O (1) (tib = 1,3,5-tris(1-imidazoly)benzene) was hydrothermally synthesized by utilizing a pH-dependent approach in the POM/Cu/tib reaction systems. X-ray structural analyses reveal that compound 1, formed in pH 5.2, possesses a (3,4,6)-connected 2D net with the (42·5)(46)(33·46·52·64) topology. In addition, electrochemical and electrocatalytic properties of compound 1 were studied by cyclic voltammograms. Compound 1 displayed electrocatalytic activities toward reduction of nitrite.
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