Abstract

One novel terbium complex [Tb 2(Dinic) 2(phen) 2(OH) 2(H 2O) 2] n · 3 nH 2O ( 1) has been synthesized by hydrothermal method, where Dinic = 3,4-pyridinedicarboxylate and phen = 1,10-phenanthroline. X-ray crystallography reveals that complex 1 possesses a one-dimensional chain structure constructed from OH − bridging binuclear units, and hydrogen bonding between chains result in a 3D network. The fluorescent properties of complex 1 were investigated in the crystal state.

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