Abstract
The crystal structure of the title compound, bis(μ-N,N-dibutyldithiocarbamato-κ2S:S′)bis[(N,N-dibutyldithiocarbamato-κ2S,S′)zinc(II)], [Zn2(C9H18NS2)4], has been determined at 180 K. The structure contains two crystallographically unique Zn2+ metal centres, showing almost identical slightly distorted tetrahedral coordination environments, and forming a dinuclear complex with two skew-bridging syn-N,N-dibutyldithiocarbamate ligands. Two other dithiocarbamate ligands are connected to the Zn2+ centres in a syn,syn-chelate coordination mode.
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