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Abstract
The Fe(III)-catalyzed ketonization of saturated hydrocarbons by tert-butyl hydroperoxide (TBHP) in pyridine-acetic acid or acetonitrile solution follows the reaction pathway alkane → alkyl hydroperoxide → ketone or alcohol. Dioxygen (O 2) is the precursor of the oxygen atoms in the alkyl hydroperoxide, the alcohol, and the ketone.
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