Abstract
Bifenthrin and fipronil are important pesticides used in the nursery industry for the control of imported fire ants. Our research measured the influence of irrigation frequency and time on the degradation of bifenthrin and fipronil in pine bark nursery medium. Pine bark media leachates were collected over a 180-d period. Levels of bifenthrin, fipronil, and metabolites of fipronil (MB 46513, MB 45950, MB 46136) were measured using gas chromatography and mass spectrophotometery. Bifenthrin leachate concentrations decreased from 60 ppb on day 1 to ≈1 ppb after 120 d. Fipronil leachate concentrations decreased from 40 ppb on day one to a low of 15 ppb after 120 d. In contrast, metabolites MB 45950 and MB 46136 gradually increased over the 180-d period. Metabolite MB 46513 was not detected during the experiment. Pine bark medium leachate concentrations of bifenthrin and fipronil were greater than previously reported levels in pure water. We theorize that organic compounds present in pine bark may have increased the solubility of these chemicals.
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