Abstract

The far-infrared laser magnetic resonance spectrum of the CD radical in the v = 0 level of the X 2Π state has been studied in detail. Twelve transitions which are accessible with currently available laser lines have been recorded. The measurements have been analyzed and subjected to a single least-squares fit using an effective Hamiltonian. The data provide primary information on the rotational and fine-structure intervals between the lowest rotational intervals. They also yield values for the Λ-type doubling and deuteron hyperfine splittings in the same levels. Combination of the measurements with the corresponding data for CH allows the two parameters, γ and A D, to be determined separately.

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