Abstract

The magnetic circular dichroism (MCD) spectra of FA(II) centres in KCl:Li crystals have been measured at a magnetic field of 11.5 kG at 17 K and room temperature. When a crystal is irradiated with linearly polarized FAl light, a non-zero circular dichroism (CD) signal is detected at zero field. The MCD spectra are compared with the zero-field CD spectra, which were obtained in systems containing both a random distribution of centres and an aligned distribution. The meaning of the MCD signal obtained in the reoriented anisotropic system using a conventional CD polarimeter is discussed.

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