Abstract
Complex formation of.C60P(O)(OPri)2 or three isomers of.C70P(O)(OPri)2 with fluorinated alcohols CF3CH2OH (1), (CF3)3COH (2), and (CF3)2CHOH (3) results in an increase in the hyperfine splitting constants with the31P nucleus by approximately 3–4 G. Only monoadducts are formed when alcohols1–3 are added to toluene saturated solutions of Hg[P(O)(OPri)2]2 and C60 under photochemical conditions of multi-addition of phosphoryl radicals to C60.
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