Abstract

In this work we study the distribution function for the total entropy production of a Brownian particle embedded in a non-Markovian thermal bath. The problem is studied in the overdamped approximation of the generalized Langevin equation, which accounts for a friction memory kernel characteristic of a Gaussian colored noise. The problem is studied in two physical situations: (i) when the particle in the harmonic trap is subjected to an arbitrary time-dependent driving force; and (ii) when the minimum of the harmonic trap is arbitrarily dragged out of equilibrium by an external force. By assuming a natural non Markovian canonical distribution for the initial conditions, the distribution function for the total entropy production becomes a non Gaussian one. Its characterization is then given through the first three cumulants.

Highlights

  • The study of fluctuation theorems (FTs) continues to be a topic of great interest in statistical mechanics of small systems out of equilibrium

  • Its validity was proven for two exactly solvable models : (i) the Brownian particle is in a harmonic trap and it is subjected to an external time-dependent force and; (ii) the minimum of the trap potential is arbitrarily dragged out of equilibrium with a time-dependent protocol

  • We must mention that the theorem for both the ordinary and charged harmonic oscillator was proven only when the initial condition is canonically distributed at equilibrium with the Markovian thermal bath

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Summary

Introduction

The study of fluctuation theorems (FTs) continues to be a topic of great interest in statistical mechanics of small systems out of equilibrium. The main results reported in [4,28,29,30], are the following: the total entropy production (TEP), denoted as ∆stot , along a single stochastic trajectory, which involves both the particle entropy and entropy production in the surrounding medium, satisfies the integral fluctuation theorem (IFT) It is expressed as he−∆stot i = 1, for canonical initial conditions when the particle is arbitrarily driven by time-dependent external forces over a finite time interval (the transient case). Our main contribution in this work is to show that when the harmonic oscillator is embedded in a non Markovian thermal bath, the change in the total entropy production presents a non-Gaussian distribution function This characteristic comes from the preparation of the system in the initial condition, which in our case is assumed to satisfy a natural non Markovian canonical distribution consistently with the non Markovian heat bath [38,39].

GLE and Stochastic Thermodynamics
Stochastic Thermodynamics
The Time-Dependent Driving Force
Dragging of the Harmonic Trap
Concluding Remarks
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