Abstract
In a recent study on oxygen-containing heterocycles, two of the current authors suggested the gas phase enthalpy of formation of 2,5-dihydrofuran in lieu of an experimentally determined quantity. The current study provides new analysis with well-precedented assumptions and literature measurements to result in the value (−63±4)kJ·mol−1. For the isomeric 2,3-dihydrofuran the value of (−77±3)kJ·mol−1 is suggested in satisfactory accord with the combustion calorimetric combustion result of (−72.2±0.4)kJ·mol−1.
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