The enhanced nucleating ability of carbon nanotube-supported β-nucleating agent in isotactic polypropylene

Abstract

A kind of β-nucleating agent, calcium pimelate, for polypropylene (PP) was chemically supported onto the surface of multi-wall carbon nanotubes, and the effect of the multi-wall carbon nanotube-supported β-nucleating agent on the mechanical properties and morphology of isotactic polypropylene composites was investigated. The composites of isotactic polypropylene and multi-wall carbon nanotube-supported β-nucleating agent exhibited excellent impact toughness compared with pure isotactic polypropylene and β-nucleated isotactic polypropylene, being more than seven times over that of pure isotactic polypropylene and more than three times over that of β-nucleated isotactic polypropylene. The excellent impact behaviors of the composites were also evidenced by the fracture morphology based on scanning electron microscopy observations. Differential scanning calorimetry and wide-angle X-ray diffraction results verified the enhanced nucleating ability of the multi-wall carbon nanotube-supported β-nucleating agent, which greatly improved the impact toughness without significantly deteriorating the strength and stiffness of the polypropylene composites.