The empty world - a view from the free volume concept and Eyring's rate process theory.

Abstract

The many-body problem is a common issue, irrespective of the scale of entities under consideration. From electrons to atoms, small molecules like simple inorganic or organic structures, large molecules like proteins or polymers, nanometer- or micrometer-sized particles, granular matter, and even galaxies, the precise determination or estimation of geometrical locations and momentum energy of individual entities, and interaction forces between these millions of entities, is impossible but unfortunately important for understanding the collective physical properties like mechanical and electrical characteristics of the whole system. Despite foreseeable difficulties and complexities, attempts to estimate "interparticle" forces have never stopped using traditional Newtonian models, quantum mechanical approaches, and density functional theory. In this review, a simple approach integrating the free volume and Eyring's rate process theory is summarized and its application across a wide range of scales from electrons to the universe is presented in a unified manner. The focus is on comparisons between theoretical predictions and experimental results.