Abstract
It is described the simple design of a series of N,N′,O,O′-chiral ligands (elpaN-salen-H2), which represent a subset of the elpaN-type library of ligands based on β-1,2-d-glucodiamine. The corresponding Mn(III) complexes were examined in the asymmetric epoxidation of styrenes with satisfactory results, e.g. cis-β-methylstyrene was functionalised in ees up to 88%.
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