Abstract

Beginning in the 1930s, G.H. Dieke and his students carried out an extensive program of measuring the optical spectrum of molecular hydrogen and its isotopes. Parts of the work were published but the project was interrupted by Dieke’s death in 1965, with much of the latest and most accurate work unpublished. This paper gives the 27 488 lines of molecular deuterium, measured by Dieke, arranges the 8243 assigned lines into band systems, and derives rotational–vibrational energy levels for over 50 electronic states. It also derives energy levels from published vacuum ultraviolet spectra of D2.

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