Abstract
The absorption spectra (190–350 nm) of trans-|Ni(m-stien) 2|L 2 and trans-|Ni(tetrameen) 2|L 2 complexes are measured for different axial ligands. The bands are assigned and the crystal field parameters are determined. The value of the D q z parameter for these complexes has been used to obtain the axial bond distances by employing the point-dipole approximation of ligand field theory and the crystal structure data of some complexes. The calculated Ni-axial ligand bond distances for some other complexes are reported.
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