Abstract
An investigation of the formation channels and properties of ionfragments following electron-impact dissociative ionization of theCCl2F2 molecule using electron kinetic energies in the 0–100 eV range isreported. Measurements of ion appearance potentials (APs) and nascenttranslational energy distributions were made on a supersonic expansion ofCCl2F2 in a time-of-flight mass spectrometer. A discussion of the correlation betweenthe channel APs, the precursor bond characters as calculated from thepopulation analysis, and the low-resolution photoelectron spectrum of theCCl2F2 molecule is presented.
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