Abstract

From the measured heat of hydrolysis of KWF6 in alkaline hypochlorite (–123·6 ± 2·6 kcal mol–1), the heat of formation of KWF6, the electron affinity of WF6, and the fluoride ion affinity of WF5 are estimated to be –541 ± 3, 120 ± 5, and 145 ± 6 kcal mol–1 respectively, at 25 °.

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