Abstract
Abstract Hydrated nickel oxide NiOxHy films were deposited onto indium tin oxide (ITO) coated glass by two methods (i) colloidal precipitation and (ii) anodic electrodeposition. The electrochromic properties of hydrated nickel oxide films were studied by transmittance measurements (UV/VIS/NIR), and Fourier transform infrared reflectance spectroscopy as a function of the key deposition parameters. The solar transmittance was calculated for films switched in both bleached and coloured states. The best results were achieved for films produced by anodic electrodeposition from stable solutions with solar transmittance Ts(bleached) = 0.82 and Ts(coloured) = 0.22. Corresponding optimum values for the films produced by colloidal precipitation were solar transmittance Ts(bleached = 0.82 and Ts(coloured) = 0.47. Fourier transform spectrophotometry was used for elucidating changes in hydration, hydroxylation and for the characterization of structural characteristics in the bleached and coloured states. It was found that free OH stretching vibration at 3647 cm−1 corresponds to Ni(OH)2 for both anodic and colloidal deposited films in the reduced (bleached) state. In the oxidised state hydrogen bonded OH at 3360 cm−1 is observed.
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