Abstract
The unsaturated mixed-metal cluster anion [{Os 3H(CO) 10} 2Ag] − has been prepared by the reaction of [(Ph 3P) 2N][Os 3H(CO) 11] with Ag[PF 6], and the anion has been shown by an X-ray analysis to consist of an Ag I atom linking together two “Os 3H(CO) 10” fragments. The electrochemistry of this complex has been investigated and it has been shown to undergo two one-electron reductions.
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