The electrochemical properties of iodine cathode in a novel rechargeable hydrogen ion supercapattery system with molybdenum trioxide as anode

Abstract

Hydrogen ion battery is a promising energy storage device due to its advantages of non-pollution, excellent rate capability and feasibility at low temperature. Herein, we assemble a novel rechargeable hydrogen ion supercapattery with the iodine-absorbed carbon paper doped with N and P (I2-NP-CP) as the cathode electrode and molybdenum trioxide as the anode electrode. Typically, the I2-NP-CP electrode shows the superior rate capability from 1 A g−1 (174.7 mAh g−1, 483.8 F g−1) to 20 A g−1 (111.1 mAh g−1, 307.7 F g−1), mainly ascribed to the strong interaction between iodine and the NP-CP substrate. Furthermore, electrochemical measurement of the I2-NP-CP@Nafion//MoO3 supercapattery manifests that the electrodes exhibit excellent cycling stability, retaining 124.3 mAh g−1 after 500 cycles at 15 A g−1, accounting for 93.2 % of the initial capacity. Although some IO3− dissolves in the electrolyte due to the weak chemical interaction between IO3− and NP-CP, and cannot be completely reduced to I− during discharge process, it can be improved by modification of electrode with Nafion resin to further better the cycling stability. The excellent electrochemical properties in this study show the possibility for the development of novel rechargeable hydrogen ion supercapattery system.