The efficient adsorption of tetracycline from aqueous solutions onto polymers with different N-vinylpyrrolidone contents: equilibrium, kinetic and dynamic adsorption.

Abstract

Extensive use of antibiotics in the world will cause potential risks to human health and ecosystems. The removal of these antibiotics has attracted much attention. Composite materials are growing attention for diverse pollutants separation and removal based on their specific functionality and surface area. In this study, a series of N-vinylpyrrolidone-divinylbenzene polymers (NVPD) with different N-vinylpyrrolidone (NVP) contents were facilely prepared for the adsorption of tetracycline (TC). The effect of polymer surface properties and aqueous solution chemistry (pH, ionic strength, humic acid) on TC adsorption was further studied. The dynamic adsorption and regeneration experiments were also assessed. The results showed that only 25% of NVP was involved in the reaction. When NVP dosage (%) was 75%, polymer (NVPD-g) owned the largest BET surface area (613.23 m2/g) and obtained the maximum TC adsorption capacities (258.76mg/g). In the kinetic, the adsorption between TC and polymers with NVP was controlled by chemical adsorption and intra-particle diffusion. The TC adsorption process of NVPD-g depended on the contribution of the hydrophobic effect, electrostatic interactions, H-bonding, π-πelectron donor-acceptor(EDA) interactions, and cation-π bonding. Moreover, the removal efficiency of TC by NVPD-g was enhanced in the presence of humic acid (HA) in the dynamic adsorption and 1197 BV (2394mL) of TC simulated wastewater can be treated. These findings suggest that NVPD-g has a potential application inthe purification of TC.