The efficiency of dodecafluoro-2-methylpentan-3-one in suppressing NCM 811 lithium-ion battery fire

Abstract

With the increase in the specific energy of lithium-ion batteries (LIBs), fire accidents occur more frequently; however, the effective and clean suppression of LIB fires remains a challenge. In the present work, the efficiency of dodecafluoro-2-methylpentan-3-one (C6F12O) in suppressing high energy density (HED) ternary LIB fires is experimentally investigated. It is found that C6F12O can efficiently extinguish the HED battery and its module fire. As the flow rate increases, the extinguishment time decreases and the peak temperature decreases, but the cooling efficiency for the long-term process is reduced. When the C6F12O spray can completely cover the thermal runaway (TR) area, its extinguishing and cooling effect is the best. For the HED module, the application of C6F12O effectively increases the TR trigger temperature, reduces the TR peak temperature, and decreases heat production. The application of water mist enhances the cooling of extinguished LIBs, the combination of C6F12O and water mist extends the TR propagation time of the fully charged LIB module to 1.4 times that without suppression, and the total TR heat production is reduced by 1423.1 kJ. These results provide guidance for the design of inhibitor volume fractions for HED LIB fires.