Abstract

The impact of the α-radiolysis of water on the corrosion potential of a UO 2 electrode has been measured in an electrochemical cell designed to bring a gold-plated α-source to within 30 μm of the UO 2 electrode. A potential of +70 mV (SCE) was obtained in the presence of a 686 μCi α-source, indicating the establishment of oxidizing conditions at the UO 2 surface. Over a period of 30 h the main process occurring appeared to be the catalytic decomposition of hydrogen peroxide to water and oxygen. Oxidation of UO 2 also occurred, but the extent of this process remains to be established.

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