The Effects of SiO2/Al2O3 and H2O/Al2O3 Molar Ratios on SAPO-34 Catalyst in the Methanol to Olefin Process

Abstract

Informed through synthesis and characterization of NH 3 TPD, BET techniques, the current study investigated the right contribution of silicon and water content on a 9 sample SAPO-34 catalyst with different molar ratios. The final prepared SAPO-34 catalytic performed reaction for the Methanol to olefin process was processed and reported at 410 0 C a reactor of fixed-bed. It was shown that catalysts with different SiO2 /Al2O3 and H2O/Al 2 O 3 ratios demonstrated high ethylene and propylene selectivity, due to their intensified crystallinity and size of crystals (1.3 to 1.7 μm). The highest degrees of ethylene and propylene selectivity for 3 samples were 50.25, 21.20, and 48.44, 19.16 respectively. Samples with ratios of different that possess high density and acute acidic sites to deactivate rapidly. The high density of acute acidic sites promoted the ultimate response to saturated hydrocarbons and aromatics based on olefins’ hydrogen transfer to and resulted in the coke generation on the top layer of the catalyst.