Abstract
The effects of quantum modes on the free energy relationship for electron-transfer reactions formulated by the ‘‘spin-boson’’ model are examined. The modified energy gap law for exothermic electron transfer reactions with quantum modes is derived in a simple analytical form, using the method of steepest descent to avoid the usual multiple convolution integrals.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
