Abstract

AbstractThe effects of the Intermolecular interaction potential on the vibrational spectra of liquids or solutions are discussed for the cases where the molecular field can be treated as a time or space‐averaged quantity. It is shown that the introduction of an appropriate molecular field can yield information about molecular properties or about molecular arrangements of component molecules in the liquid and solution phases. Certain spectral characteristics, for instance absorption intensity in infra‐red spectra and scattering cross‐section and depolarization ratio in Raman spectra, are discussed.

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