The effects of in-situ ZrB2 particles and Gd on the solidification behavior and mechanical properties of AA6111 matrix composites

Abstract

In this research work, the new AA6111 matrix composites reinforced by the cooperation of nano ZrB2 particles and Gd had been designed and fabricated via in situ reaction. The addition of Gd made the nano ZrB2 particles uniformly dispersed due to the reduction of solid-particle interfacial energy (σsp) by keeping the low-energy orientation relationship. Meanwhile, it promotes the formation of equiaxed grains whose formation is also based on the nano-sized reinforcing phases as the hindering of dendrite coherency points are related to the growth restriction factor (GRF) and as the pinning effect to the grain boundaries. The fluidity was improved because of uniform viscosity and dendrites avoided meeting with the neighboring ones by the entrapment of nano-sized reinforcing phases like AlGd and ZrB2. The results indicated that AA6111–0.5 wt. % Gd-2 vol. % ZrB2 composites possessed the longest fluidity length of 70 mm. Meanwhile, the composites displayed increases of 32.7 %, 47.3 % and 52.8 % in YS, UTS and elongation, respectively, compared to the matrix alloy. A notable lattice distortion of the matrix near the ZrB2 particles and AlGd phases was proclaimed via Geometric Phase Analysis (GPA) analysis. Strengthening mechanism comprehending yield strength, containing Orowan strengthening, grain refinement strengthening, was integrally elaborated.