The effects of biochar/compost for adsorption behaviors of sulfamethoxazole in amended wetland soil.

Abstract

Biochar and compost were two common amendments for the polluted soil. However, few studies were conducted to study the sorption of organic pollutants on combined biochar-compost and the relative adsorption mechanisms in mixed soil. The work had studied the adsorption and desorption behaviors of sulfamethoxazole (SMX) onto wetland soil after amended with biochar and/or compost. Moreover, the physicochemical and morphology properties of biochar/compost and amended soils were analyzed to discuss the relative adsorption mechanisms. Studies showed that the adsorption capacity of amended soils increased with the total amount of biochar or/and compost added, which was positively related to SOM, CEC, and EC of amended soils, but had nothing to do with the type of additives. Compared with the compost-treated treatments, the biochar-treated treatments generally achieved lower desorption rates, which also had demonstrated both different adsorption mechanisms. Pore filling and hydrophobic partitioning were the main adsorption mechanisms for biochar and compost, respectively. Though biochar owned developed pore structure, however, pore-filling of biochar was overwhelmingly weakened due to pore-blocking in mixed soils. Hence, in soil environment, compost is a kind of a more desirable amendment than biochar in absorbing and degrading organic pollutants.