Abstract

AbstractThe initial polymerization rate of ethyl, butyl, and 2‐ethylhexyl acrylate was studied in a thermally insulated polymerization reactor. The monomers were continuously added into the reactor and the effect of concentration of anionic emulsifiers on the temperature increase was investigated.Alkyl(aryl)polyethylenglykolethersulfate were found to be most effective in promoting the initial polymerization rate. An inhibition action of some emulsifiers was found.

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