Abstract
The isomerization of readily available allyl ethers catalyzed by soluble ruthenium complexes is an extremely versatile methodology for synthesis of O-1-propenyl systems—attractive monomers in cationic UV-radiation curing technology. From the process development perspective, the effectiveness of selected simple ruthenium catalyst precursors, mainly [RuClH(CO)(PPh 3) 3], [RuCl 2(PPh 3) 3] and RuCl 3· xH 2O in the solvent-free isomerization of 1,4-bisallyloxybutane has been examined. The relationship between basic reaction parameters such as the reaction temperature, the amount of catalyst precursor, the promoters of non-hydride complexes (bases or alcohols), the ambient gas atmosphere and the reaction time allowing to achieve quantitative conversion of the model bisallyl ether to its 1-propenyl derivatives ( τ 100%) has been presented. Particular attention has been paid to the use of lower loadings of [Ru] complex required for the completion of the reaction within the reasonable times. For the first time a detailed study on the effect of the presence and amount of allyl hydroperoxides on the course of isomerization has been done.
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