The effectiveness and adsorption mechanism of iron-carbon nanotube composites for removing phosphate from aqueous environments

Abstract

This study successfully employed iron-carbon nanotubes (Fe-CNT) to recover phosphate (P) from water. We examined the effects of various iron concentrations denoted by Fe-CNT-1 and Fe-CNT-2 on P removal and compared them with pristine carbon nanotubes (CNTs). The adsorption capacity of Fe-CNTs was much better than pristine CNTs. According to the high adsorption capacity, Fe-CNT-2 sample was very effective for P recovery and exhibits ∼7 times higher P removal efficiency than that of pristine CNTs. The characterization of the as-obtained adsorbent (Fe-CNT-2) and pristine CNTs were performed using X-ray diffraction, Brunauer–Emmett–Teller method, Field emission scanning electron microscope coupled with energy-dispersive spectroscopy detector (FESEM-EDS), X-ray photoelectron spectroscopy and Transmission electron microscopy. Results demonstrated that iron oxide nanoparticles were successfully deposited on the surface of CNT. The adsorption kinetics and isotherm studies for P removal showed pseudo-second-order rate constants (R2 > 0.99) and the Langmuir isotherm (R2 > 0.99) respectively, thus revealing that the nature of adsorption was chemisorption. The estimated Langmuir adsorption capacity of Fe-CNT-2 was 36.5 mgP/g or 112 mg PO4/g at an equilibrium time of 3 h. The ionic strength provided by SO42−, NO3−, and Cl− demonstrated no considerable influence on phosphate adsorption. Moreover, the P adsorbed Fe-CNT-2 was efficiently recovered with different concentrations of desorbing reagents, such as NaOH and NaCO32−. Moreover, the findings of X-ray photoelectron spectroscopy (XPS) analysis demonstrated that OH group played a major role in the P removal by Fe-CNT-2. The findings of this study demonstrate that Fe-CNT-2 had a great deal of application as an effective and stable adsorbent for the P recovery from aquatic environments.