Abstract
If uncompensated resistance is ignored, the standard rate constant, k s and the transfer coefficient α, as determined by the usual potential-step method, will both be too small. The error may not be large, however, provided that k s < 2 · 10 −2 cm sec −1 and that the experiment is designed to minimize the uncompensated resistance effects. A method is described by which α and K s may be determined in the presence of uncompensated resistance; the method may be used for K s magnitudes as large as 0.15 cm sec −1.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
