Abstract
Objectivesto complement our previous work by testing the null hypotheses that with short curing times and high DC, TPO-based resin composites would exhibit (1) higher polymerization stresses and consequently display (2) higher temperature rise and (3) higher flexural modulus, flexural strength and hardness, compared to a conventional CQ-based experimental composite. MethodsTwo experimental resin composites using either Lucirin-TPO or camphorquinone/DMAEMA as photoinitiators were prepared. Light curing was carried out using spectral outputs adapted to the absorption properties of each initiator. Different irradiation protocols were selected (0.5, 1, 3, 9s at 500, 1000 and 2000mW/cm2 for Lucirin-TPO based composites and 20 or 40s at 1000mW/cm2 for Lucirin-TPO and camphorquinone-based composites). Degree of conversion (DC) was measured in real time by means of FT-NIR spectroscopy. Pulpal temperature rise (ΔT) was studied in a tooth model. Polymerization stress was monitored using the Bioman instrument. For cured specimens, flexural modulus and flexural strength were determined using a three point bending platform and Vickers hardness was determined with a microhardness indentor on samples prior to and after 24h incubation in 75/25 ethanol/H2O. Premolars were restored with both materials and microleakage at the teeth/composite interfaces following restoration was assessed. ResultsLucirin-TPO-based composites irradiated at radiant exposures of 3J/cm2 and more exhibited significantly higher DCs, associated with increased flexural moduli and hardness compared to CQ-based composites. For an ultra-short irradiation time of 1s at 1000mW/cm2, TPO-composites displayed similar polymerization stresses compared to CQ-controls with yet a 25% increase for flexural modulus and 40% increase for hardness measured after EtOH/H2O sorption. Higher stress rates were however observed in all curing protocols compared to CQ-composites. Microleakage was similar between TPO and CQ-composites irradiated at 1000mW/cm2 for 3 and 20s respectively, while a significant increase was observed for TPO-composites irradiated for 1s. ΔT measured through a 0.6mm thick dentin layer were all below 5.5°C; TPO-composites exhibited similar or lower values compared to controls. SignificanceThe use of Lucirin-TPO in resin composites along with appropriate curing conditions may allow for a major reduction of irradiation time while improving mechanical properties. The amount of stress observed during polymerization in TPO-based composites can be similar to those using CQ and the cohesion at the restoration-tooth interface was not affected by short curing times. Contrary to other studies, we found that the temperatures increases measured during polymerization were all well below the 5.5°C threshold for the pulp.
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