Abstract
One of the most useful polymeric materials at industrial scale is plasticized polyvinyl chloride (P-PVC) or PVC plastisol. This is characterized by optimum balance among processing conditions, overall properties, cost, and versatility; however, it has some problems related to plasticizer migration (generally phthalates derivatives) with toxicity problems. As a consequence of the appearance of new regulations which restrict the use of phthalates, the study of new plasticizers with low toxicity and low migration has become a very interesting research field. In this study, the optimum curing conditions of vinyl plastisols with a natural-based epoxidized fatty acid ester as plasticizer have been investigated by the following mechanical properties: thermal behavior, color changes, solvent migration, and microstructure changes in terms of the curing conditions. This study was carried out with a plasticizer content of 70 phr (per hundred resin); different isothermal curing conditions ranging from 160 to 220 °C, and curing times in the 6–10 min range were used. The results revealed that the best curing conditions are 200 and 220 °C for curing times near to 14 and 10 min, respectively, which are similar to those used for other commonly used plasticizers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.