The Effect of Temperature and Pressure on the Reversibility of Asphaltene Precipitation

Abstract

A lot of hindrances are seen in petroleum operation, production, and transportation as a results of factors that related to asphaltene precipitation. It has great importance to investigate the reversibility of asphaltene precipitation under changes of effective factors on thermodynamic conditions such as pressure, temperature, and composition. In the present work the reversibility of asphaltene precipitation under changes of pressure and temperature was investigated for two kind of Iranian heavy oil. The stability test shows these samples are located at unstable region in aspect of asphaltene precipitation. The experimental procedure includes two parts, (a) decreasing pressure from initial reservoir pressure to near saturation pressure and surveying asphaltene content hysteresis with redissolution process at reservoir temperature, and (b) investigation of precipitated asphaltene in both precipitation and redissolution processes at different temperature and reservoir pressure. At each step IP143 standard test was used to measure precipitated asphaltene. It was concluded that above bubble point pressure, asphaltene precipitation is nearly reversible with respect to pressure for both samples and it was partially reversible with respect to the temperature for sample A, and accordingly pressurizing is acceptable method for solving the problem in both heavy asphaltenic crude oil samples and increasing temperature is acceptable method for solving asphaltene problem in crude oil sample A. Also density measurement of flashed oil confirmed that there is a little hysteresis in asphaltene content during redissolution and precipitation processes.