The Effect of Synthetic Zeolite on the Curing Process and the Properties of the Natural Rubber-Based Composites.

Abstract

Zeolites, known for their unique structural and catalytic properties, are added to the natural rubber matrix to investigate their influence on the vulcanization process and the resultant properties of composites. The natural rubber-based composites were masticated with 4A synthetic zeolite (0, 5, 10, 15, 20, and 30 phr). The curing of the rubber compounds was monitored on a moving die rheometer at 150 °C. The isothermal DSC method was also used to study the curing process at 150 °C, 160 °C, and 170 °C. Based on the obtained results, it is assumed that there is an interaction between the components of the curing system and the surface of the zeolite particle, and that is why the vulcanization reaction starts earlier with an increase in zeolite in the rubber mixture. This underscores the significant role of zeolite in accelerating the curing reaction of natural rubber-based compounds. The composites were vulcanized in a press at 150 °C for 15 min. The chemical structure was analyzed using FTIR, and the sample morphology was examined using SEM. The degree of swelling in toluene and distilled water was determined. The tensile strength values, modulus of elasticity at 100% and 300% elongation, and elongation at break were measured using a universal testing machine. Hardness was assessed according to the Shore A scale. With a small addition of zeolite (up to 10 phr), there is no significant change in the tensile strength values. However, adding a considerable amount of zeolite to a natural rubber matrix results in a deterioration of the tested mechanical properties. It can be assumed that with large proportions of zeolite 4A MS in the composites, the mechanical properties deteriorated due to increased porosity. The amount of added zeolite affects the initial stages of thermal decomposition of the examined samples and the rest after the analysis at a temperature of 500 °C.